NIOSH Pocket Guide to Chemical Hazards

Methyl chloride CAS 74-87-3
CH3Cl RTECS PA6300000
Synonyms & Trade Names
Chloromethane, Monochloromethane
DOT ID & Guide
1063 115
Exposure
Limits
NIOSH REL: Ca See Appendix A
OSHA PEL†: TWA 100 ppm C 200 ppm 300 ppm (5-minute maximum peak in any 3 hours)
IDLH Ca [2000 ppm] See: 74873 Conversion 1 ppm = 2.07 mg/m3
Physical Description
Colorless gas with a faint, sweet odor which is not noticeable at dangerous concentrations. [Note: Shipped as a liquefied compressed gas.]
MW: 50.5
BP: -12°F
FRZ: -144°F
Sol: 0.5%
VP: 5.0 atm
IP: 11.28 eV
RGasD: 1.78

Fl.P: NA (Gas)
UEL: 17.4%
LEL: 8.1%

Flammable Gas
Incompatibilities & Reactivities
Chemically-active metals such as potassium, powdered aluminum, zinc & magnesium; water [Note: Reacts with water (hydrolyzes) to form hydrochloric acid.]
Measurement Method
Charcoal tube(2); CH2Cl2; Gas chromatography/Flame ionization detection; IV [#1001] See: NMAM INDEX
Personal Protection & Sanitation
Skin: Frostbite
Eyes: Frostbite
Wash skin: N.R.
Remove: When wet (flammable)
Change: N.R.
Provide: Frostbite
First Aid (See procedures)
Eye: Frostbite
Skin: Frostbite
Breathing: Respiratory support

Respirator Recommendations NIOSH
At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, skin and/or eye contact (liquid)
Symptoms dizziness, nausea, vomiting; visual disturbance, stagger, slurred speech, convulsions, coma; liver, kidney damage; liquid: frostbite; reproductive, teratogenic effects; [Potential occupational carcinogen]
Target Organs central nervous system, liver, kidneys, reproductive system

Cancer Site [in animals: lung, kidney & forestomach tumors]
See also: INTRODUCTION   See ICSC CARD: 0419   See MEDICAL TESTS: 0140